Synthesis of 2,3-dihydropolyprenyl H-phosphonates and thiophosphates
L. L. Danilov, S. D. Maltsev, V. N. Shibaev
N. D. Zelinsky Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow
Abstract: Dolichyl and citronellyl H-phosphonates were prepared in 90 and 50% yields, respectively, by reaction of the alcohols with triimidazolyl phosphite. Dolichyl O-thiopho-sphate was obtained via interaction of dolichol with thiophosphoryl chloride and pyri-dine in a yield of 56%.
Russian Journal of Bioorganic Chemistry 1991, 17 (9):1292-1293