A simple method for the synthesis of glycosyl diglycerides
A. V. Lyubeshkin, Yu. L. Sebyakin, R. P. Evstigneeva
M. V. Lomonosov Institute of Fine Chemical Technology, Moscow
Abstract: A one-step method for preparation of glycosyl glycerols, important intermediates in the synthesis of glycosyl diglycerides, is described. The method is based on glyco-sylation of sugar peracetates with isopropylidene-rac-glycerol in the presence of Lewis acids. Syntheses of some dipalmitoyl-gliceryl mono- and diglycosides are described.
Russian Journal of Bioorganic Chemistry 1991, 17 (5):710-713