The mechanism of phosphorylation of alcohols with tetra-n-butylammonium dihydrogen phosphate and trichloroacetonitrile
L. L.Danilov, S. D. Maltsev, V. N. Shibaev
N. D. Zelinsky Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow
Abstract: The reaction of tetra-n-butylammonium dihydrogen phosphate and trichloroaceto-nitrile in dry chloroform was studied with the use of 31P NMR spectroscopy. The results obtained are consistent with the intermediate formation of metaphosphate-anion in the reaction. The course of the reaction differed from the analogous reaction with tri-n-butylammonium dihydrogen phosphate as the reagent.
Russian Journal of Bioorganic Chemistry 1990, 16 (10):1423-1425